The progress in synthesis of chiral mandelic acid and resolution of racemic mandelic acid are reviewed. 综述了手性扁桃酸的合成及外消旋扁桃酸拆分的研究进展。
METHODS: The acetylized racemic mixture of D-penicillamine was prepared by racemizing acetyl chloride in acetic acid solu_tion with D-penicillamine as feedstock. 方法以D-青霉胺为原料,在醋酸溶液中,用乙酰氯为酰化试剂进行消旋化,得到了D-青霉胺酰化消旋物;
Study on the racemic theory of essential amino acid and protein nutrition 必需氨基酸消旋化理论的研究与蛋白质营养
Resolution of racemic 2-( 9-anthranyl)-2-hydroxyacetic acid and its derivations 2-(9-蒽基)-2-羟基乙酸及其衍生物的外消旋体拆分
Glycidyl butyrate was synthesized from racemic epichlorohydrin and butyric acid by chemical means. The purity of the refined product was over 96% and the yield was about 47%. 利用化学方法,由外消旋环氧氯丙烷出发,合成丁酸环氧丙酯,精制后可获得纯度96%以上的丁酸环氧丙酯,收率为47%。
Enantioselective esterification of racemic ketoprofen [ 2 ( 3 benzoylphenyl) propionic acid] was carried out in organic solvents by using celite adsorbed lipase as the catalyst. 以硅藻土吸附的脂肪酶为催化剂,对外消旋酮基布洛芬〔2-(3-苯甲酰苯基)丙酸〕进行对映选择性酯化反应;